| 1 |  Luciano André Pagliarini Mendonca (BRA) | Lampre - Fondital | 4.01.30 (46.46 km/h) |
| 2 |  Massimo Strazzer (ITA) | Phonak Hearing Systems | zt |
| 3 |  Alexei Markov (RUS) | Lokomotiv | zt |
| 4 |  Bram De Groot (NED) | Rabobank | zt |
| 5 | Marc Lotz (NED) | Rabobank | zt |
| 6 |  Iban Herrero Atienzar (ESP) | Labarca-2 - Cafes Baque | zt |
| 7 | Francisco Gutierrez Alvarez (ESP) | Labarca-2 - Cafes Baque | zt |
| 8 |  Ruslan Ivanov (MDA) | Alessio | zt |
| 9 |  Nico Sijmens (BEL) | Vlaanderen - T Interim | zt |
| 10 | Angel Edo Alsina (ESP) | Milaneza - Mss | zt |
| 11 |  Milan Kadlec (CZE) | Lampre - Fondital | zt |
| 12 |  Rui Miguel Sousa Barbosa (POR) | Milaneza - Mss | zt |
| 13 | Alejandro Valverde Belmonte (ESP) | Kelme - Costa Blanca | zt |
| 14 | Nikita Eskov (RUS) | Lokomotiv | zt |
| 15 | Mariano Piccoli (ITA) | Lampre - Fondital | zt |
| 16 | Xabier Zandio Echaide (ESP) | Ibanesto.com | zt |
| 17 | Mikel Artetxe Guezuraga (ESP) | Euskaltel - Euskadi | zt |
| 18 | Matthew Gilmore (BEL) | Vlaanderen - T Interim | zt |
| 19 | Ricardo Serrano Gonzalez (ESP) | Labarca-2 - Cafes Baque | zt |
| 20 | David Fernandez Domingo (ESP) | Colchon Relax - Fuenlabrada | zt |
| 21 | Oleg Rodionov (RUS) | Lokomotiv | zt |
| 22 | Constantino Zaballa Gutierrez (ESP) | Kelme - Costa Blanca | zt |
| 23 | David Lopez Garcia (ESP) | Labarca-2 - Cafes Baque | zt |
| 24 |  Alexandre Usov (BLR) | Phonak Hearing Systems | zt |
| 25 | Jose Ivan Gutierrez Palacios (ESP) | Ibanesto.com | zt |
| 26 | Rubén Plaza Molina (ESP) | Ibanesto.com | zt |
| 27 | Ángel Vicioso Arcos (ESP) | O.N.C.E. - Eroski | zt |
| 28 | Carlos Torrent Tarres (ESP) | Paternina - Costa de Almeria | zt |
| 29 |  Bobby Julich (USA) | Deutsche Telekom | zt |
| 30 | Wim Van Huffel (BEL) | Vlaanderen - T Interim | zt |
| 31 | Jurgen Van De Walle (BEL) | Vlaanderen - T Interim | zt |
| 32 | Nacor Burgos Rojo (ESP) | Colchon Relax - Fuenlabrada | zt |
| 33 | Carlos Ramon Golbano Garcia (ESP) | Paternina - Costa de Almeria | zt |
| 34 | Serguei Klimov (RUS) | Lokomotiv | zt |
| 35 |  Gustavo Mario Toledo Britos (ARG) | Paternina - Costa de Almeria | zt |
| 36 | Rui Lavarinhas (POR) | Milaneza - Mss | zt |
| 37 | Denis Smyslov (RUS) | Lokomotiv | zt |
| 38 | Thorwald Veneberg (NED) | Rabobank | zt |
| 39 |  Grischa Niermann (GER) | Rabobank | zt |
| 40 | Julian Usano Martinez (ESP) | Kelme - Costa Blanca | zt |
| 41 | Steven Kleynen (BEL) | Vlaanderen - T Interim | zt |
| 42 | Rafael Casero Moreno (ESP) | Paternina - Costa de Almeria | zt |
| 43 |  Cadel Evans (AUS) | Deutsche Telekom | zt |
| 44 | Jose Luis Arrieta Lujambio (ESP) | Ibanesto.com | zt |
| 45 | Angelo Lopeboselli (ITA) | Cofidis | zt |
| 46 | Iker Flores Galarza (ESP) | Euskaltel - Euskadi | zt |
| 47 | Pavel Brutt (RUS) | Lokomotiv | zt |
| 48 | Bingen Fernandez Bustinza (ESP) | Cofidis | zt |
| 49 | José Enrique Gutiérrez Cataluña (ESP) | Kelme - Costa Blanca | zt |
| 50 | Isidro Nozal Vega (ESP) | O.N.C.E. - Eroski | zt |
| 51 | Antonio Colom Mas (ESP) | Colchon Relax - Fuenlabrada | zt |
| 52 | German Nieto Fernandez (ESP) | Colchon Relax - Fuenlabrada | zt |
| 53 | Hector Guerra Garcia (ESP) | Colchon Relax - Fuenlabrada | zt |
| 54 |  Rudolf Wentzel (RSA) | Vlaanderen - T Interim | zt |
| 55 | Frederik Willems (BEL) | Vlaanderen - T Interim | zt |
| 56 |  Alexander Vinokourov (KAZ) | Deutsche Telekom | zt |
| 57 | Iban Mayo Díez (ESP) | Euskaltel - Euskadi | zt |
| 58 | Domingo José Sanchez Segado (ESP) | Paternina - Costa de Almeria | zt |
| 59 | Oscar Laguna Garcia (ESP) | Colchon Relax - Fuenlabrada | zt |
| 60 | Haimar Zubeldia Aguirre (ESP) | Euskaltel - Euskadi | zt |
| 61 | Jef Peeters (BEL) | Vlaanderen - T Interim | zt |
| 62 | Juan Carlos Guillamon Ruiz (ESP) | Paternina - Costa de Almeria | zt |
| 63 | David Etxebarria Alkorta (ESP) | Euskaltel - Euskadi | zt |
| 64 | Rafael Diaz Justo (ESP) | O.N.C.E. - Eroski | zt |
| 65 | Matthias Kessler (GER) | Deutsche Telekom | zt |
| 66 | Andreas Klöden (GER) | Deutsche Telekom | zt |
| 67 | Francisco Perez Sanchez (ESP) | Milaneza - Mss | zt |
| 68 | Stefan Kupfernagel (GER) | Phonak Hearing Systems | zt |
| 69 | Jose Manuel Maestre Rodriguez (ESP) | Colchon Relax - Fuenlabrada | zt |
| 70 | Denis Lunghi (ITA) | Alessio | 0.12 |
| 71 |  Michael Rasmussen (DEN) | Rabobank | 0.15 |
| 72 | Alexander Serov (RUS) | Lokomotiv | zt |
| 73 | Bert Grabsch (GER) | Phonak Hearing Systems | 0.18 |
| 74 | Jan Hruska (CZE) | O.N.C.E. - Eroski | zt |
| 75 | Adolfo Garcia Quesada (ESP) | Kelme - Costa Blanca | 0.26 |
| 76 | Carlos Garcia Quesada (ESP) | Kelme - Costa Blanca | zt |
| 77 | Leandro Navarrete Gutierrez (ESP) | Labarca-2 - Cafes Baque | 0.33 |
| 78 | Lizuarte Manuel Goncalves Martins (POR) | Milaneza - Mss | zt |
| 79 | Mario Aerts (BEL) | Deutsche Telekom | 0.35 |
| 80 | Francisco Palacios San Emeterio (ESP) | Labarca-2 - Cafes Baque | 0.43 |
| 81 | Unai Osa Eizaguirre (ESP) | Ibanesto.com | zt |
| 82 | Joan Sebastian Horrach Rippoll (ESP) | Milaneza - Mss | 0.48 |
| 83 | Juan Miguel Mercado Martin (ESP) | Ibanesto.com | zt |
| 84 | José Manuel Vázquez Palomo (ESP) | Colchon Relax - Fuenlabrada | zt |
| 85 | Jonathan Gonzalez Rios (ESP) | O.N.C.E. - Eroski | zt |
| 86 | David Herrero Llorente (ESP) | Euskaltel - Euskadi | zt |
| 87 | José Luis Martinez Jimenez (ESP) | Paternina - Costa de Almeria | zt |
| 88 | Iker Camano Ortuzari (ESP) | Phonak Hearing Systems | zt |
| 89 | Leonardo Piepoli (ITA) | Ibanesto.com | zt |
| 90 | Marcelino Garcia Alonso (ESP) | Labarca-2 - Cafes Baque | zt |
| 91 | Serguei Yakovlev (KAZ) | Deutsche Telekom | zt |
| 92 | César Garcia Calvo (ESP) | Labarca-2 - Cafes Baque | zt |
| 93 | Andrei Kivilev (KAZ) | Cofidis | zt |
| 94 | Addy Engels (NED) | Rabobank | zt |
| 95 | Pietro Caucchioli (ITA) | Alessio | zt |
| 96 | Levi Leipheimer (USA) | Rabobank | 2.04 |
| 97 | Gorka Beloki Dorronsoro (ESP) | O.N.C.E. - Eroski | zt |
| 98 | Gonzalo Bayarri Esteve (ESP) | Phonak Hearing Systems | zt |
| 99 |  Alexandre Moos (SUI) | Phonak Hearing Systems | 2.20 |
| 100 | Álvaro González de Galdeano Aranzábal (ESP) | O.N.C.E. - Eroski | 4.53 |
| 101 | Lander Euba Ziarrusta (ESP) | Euskaltel - Euskadi | zt |
