| 1 |  Nairo Alexander Quintana Rojas (COL) | Movistar | 05:06:10 |
| 2 |  Jonathan Tiernan-Locke (GBR) | Endura Racing | 00:06 |
| 3 |  Wout Poels (NED) | Vacansoleil - DCM | 00:09 |
| 4 |  Sergio Pardilla Bellón (ESP) | Movistar | 00:15 |
| 5 | Nicolas Jonathan Castroviejo (ESP) | Movistar | 00:21 |
| 6 | Samuel Sanchez Gonzalez (ESP) | Euskaltel - Euskadi | 00:22 |
| 7 | Johnny Hoogerland (NED) | Vacansoleil - DCM | 00:25 |
| 8 | Robert Gesink (NED) | Rabobank | 00:33 |
| 9 |  Bartosz Huzarski (POL) | Team Netapp | 00:47 |
| 10 |  Paul Voss (GER) | Endura Racing | 01:24 |
| 11 | Adrian Palomares Villaplana (ESP) | Andalucia | 01:26 |
| 12 |  Vladimir Karpets (RUS) | Movistar | 01:53 |
| 13 |  Sander Armée (BEL) | Topsport Vlaanderen - Mercator | 02:03 |
| 14 | Garikoitz Bravo Oiarbide (ESP) | Caja Rural | 02:07 |
| 15 |  Daniel Andonov Petrov (BUL) | Caja Rural | 02:08 |
| 16 | Kirill Sveshnikov (RUS) | Lokosphinx | 02:23 |
| 17 | Iker Camano Ortuzari (ESP) | Endura Racing | 02:24 |
| 18 | Jesús Herrada Lopez (ESP) | Movistar | 02:42 |
| 19 |  Matthias Brändle (AUT) | Team Netapp | 02:47 |
| 20 |  Andreas Dietziker (SUI) | Team Netapp | 02:53 |
| 21 | Antonio Piedra Perez (ESP) | Caja Rural | 02:58 |
| 22 | Ivan Rovny (RUS) | Rusvelo | 03:03 |
| 23 | Stef Clement (NED) | Rabobank | 03:04 |
| 24 | Pieter Serry (BEL) | Topsport Vlaanderen - Mercator | zt |
| 25 |  André Fernando Martins Cardoso (POR) | Caja Rural | 03:35 |
| 26 | Johannes Fröhlinger (GER) | Argos - Shimano | 03:37 |
| 27 | Javier Chacón Quesada (ESP) | Andalucia | 03:39 |
| 28 | Markus Fothen (GER) | Nsp - Ghost | 03:44 |
| 29 | Erick Rowsell (GBR) | Endura Racing | 03:46 |
| 30 | Amets Txurruka Ansola (ESP) | Euskaltel - Euskadi | 03:50 |
| 31 | David Da Silva Livramento (POR) | Carmin - Prio | 03:51 |
| 32 | Omar Fraile Matarranz (ESP) | Orbea | 03:52 |
| 33 | Iban Velasco Murillo (ESP) | Euskaltel - Euskadi | 03:58 |
| 34 | Tom Jelte Slagter (NED) | Rabobank | zt |
| 35 | Rob Ruijgh (NED) | Vacansoleil - DCM | 03:59 |
| 36 | Marek Rutkiewicz (POL) | CCC - Polkowice | 04:01 |
| 37 | Sergio Mantecon Gutierrez (ESP) | | 04:03 |
| 38 | Andrés Vigil Vidal (ESP) | Andalucia | 04:04 |
| 39 | Jaume Rovira Pous (ESP) | Gios - Deyser | 04:05 |
| 40 | Rubén Fernández Andújar (ESP) | Caja Rural Amateur | 04:20 |
| 41 | Pieter Jacobs (BEL) | Topsport Vlaanderen - Mercator | 04:30 |
| 42 | Wilco Kelderman (NED) | Rabobank | 04:31 |
| 43 | Samuel Nicolas (ESP) | | 04:33 |
| 44 |  Damien Branaa (FRA) | Burgos - BH - Castilla y Leon | 04:41 |
| 45 | Jóni Silva Brandão (POR) | Burgos - BH - Castilla y Leon | 05:06 |
| 46 | Nicolas Capdepuy (FRA) | Burgos - BH - Castilla y Leon | 05:15 |
| 47 | Matthieu Sprick (FRA) | Argos - Shimano | 05:25 |
| 48 | Henrique Madeira Casimiro (POR) | Carmin - Prio | 05:36 |
| 49 | Aitor Perez Arrieta (ESP) | | 05:38 |
| 50 | Rubén Plaza Molina (ESP) | Movistar | 05:44 |
| 51 | Sergey Belykh (RUS) | Lokosphinx | 06:01 |
| 52 |  Tobias Ludvigsson (SWE) | Argos - Shimano | 06:25 |
| 53 | Jorge Azanza Soto (ESP) | Euskaltel - Euskadi | 06:26 |
| 54 | Pedro Merino Criado (ESP) | Gios - Deyser | 06:27 |
| 55 | Alexei Kunshin (RUS) | Lokosphinx | 06:29 |
| 56 | Mikel Nieve Iturralde (ESP) | Euskaltel - Euskadi | 06:36 |
| 57 | Evgeny Shalunov (RUS) | Lokosphinx | 06:58 |
| 58 | Juan Jose Cobo Acebo (ESP) | Movistar | 06:59 |
| 59 | Salvador Guardiola Tora (ESP) | Gios - Deyser | 07:12 |
| 60 | Pablo Lechuga Rodriguez (ESP) | Andalucia | 07:23 |
| 61 | Aritz Bagües Kalparsoro (ESP) | Orbea | 07:26 |
| 62 | Sergey Shilov (RUS) | Lokosphinx | 07:28 |
| 63 | Mikel Bizkarra Etxeguibel (ESP) | Orbea | 07:35 |
| 64 | Carlos Verona Quintanilla (ESP) | Burgos - BH - Castilla y Leon | 07:40 |
| 65 |  Cesare Benedetti (ITA) | Team Netapp | 07:48 |
| 66 | Martijn Keizer (NED) | Vacansoleil - DCM | 07:53 |
| 67 | Alexander Wetterhall (SWE) | Endura Racing | 07:55 |
| 68 | Dmitriy Sokolov (RUS) | Lokosphinx | 07:59 |
| 69 | Jarl Salomein (BEL) | Topsport Vlaanderen - Mercator | 08:16 |
| 70 | Kevin De Jonghe (BEL) | Topsport Vlaanderen - Mercator | 08:24 |
| 71 | Alejandro Manuel Marque Porto (ESP) | Carmin - Prio | 08:27 |
| 72 | Ricardo Jorge Correia Mestre (POR) | Carmin - Prio | 08:53 |
| 73 | Hernâni Brôco (POR) | Caja Rural | 08:55 |
| 74 | Lluís Guillermo Mas Bonet (ESP) | Burgos - BH - Castilla y Leon | 09:02 |
| 75 | Miguel Minguez Ayala (ESP) | Euskaltel - Euskadi | 09:21 |
| 76 | Dariusz Batek (POL) | CCC - Polkowice | 09:35 |
| 77 | Tomasz Marczynski (POL) | Vacansoleil - DCM | 09:46 |
| 78 | Artur Ershov (RUS) | Rusvelo | 09:47 |
| 79 | Roger Kluge (GER) | Argos - Shimano | 10:17 |
| 80 | Tomasz Kiendys (POL) | CCC - Polkowice | 10:19 |
| 81 | David Belda Garcia (ESP) | Burgos - BH - Castilla y Leon | 10:29 |
| 82 |  Jan Bárta (CZE) | Team Netapp | 11:12 |
| 83 | Jos Van Emden (NED) | Rabobank | 11:28 |
| 84 | Thomas Bonnin (FRA) | Argos - Shimano | 11:35 |
| 85 | Jacob Fiedler (GER) | Nsp - Ghost | 11:38 |
| 86 | Igor Merino Cortázar (ESP) | Orbea | 11:39 |
| 87 | Jonathan Gonzalez Gonzalez (ESP) | Gios - Deyser | 11:46 |
| 88 | Nelson Nuno Sequeria Vitorino (POR) | Carmin - Prio | 11:54 |
| 89 | Alexander Serov (RUS) | Rusvelo | 12:12 |
| 90 | Léo Menville (FRA) | Nsp - Ghost | 12:36 |
| 91 | Julian Sanchez Pimienta (ESP) | Caja Rural | 12:40 |
| 92 | João Mendonça Pereira (POR) | Carmin - Prio | 12:50 |
| 93 | Francisco Jose Pacheco Torres (ESP) | Gios - Deyser | 13:16 |
| 94 | Eloy Ruiz Pinto (ESP) | Andalucia | 13:21 |
| 95 | Thierry Hupond (FRA) | Argos - Shimano | 13:28 |
| 96 | Jon Aberasturi Izaga (ESP) | Orbea | 13:36 |
| 97 | Jose Luis Roldan Carmona (ESP) | Andalucia | 13:53 |
| 98 | David De La Fuente Rasilla (ESP) | Caja Rural | zt |
| 99 | Jose Rafael Martinez Castillo (ESP) | | 13:54 |
| 100 | Eloy Teruel Rovira (ESP) | | 14:40 |
| 101 | Gustavo César Veloso (ESP) | Andalucia | 15:01 |
| 102 | Sergej Fuchs (GER) | Nsp - Ghost | 15:05 |
| 103 |  Zakkari Dempster (AUS) | Endura Racing | 15:09 |
| 104 |  Yukihiro Doi (JAP) | Argos - Shimano | 15:52 |
| 105 | Kenny De Ketele (BEL) | Topsport Vlaanderen - Mercator | 16:03 |
| 106 | Francisco Manuel Anton Marin (ESP) | Burgos - BH - Castilla y Leon | 16:10 |
| 107 | Bartlomiej Matysiak (POL) | CCC - Polkowice | 16:42 |
| 108 | Mateusz Taciak (POL) | CCC - Polkowice | 16:59 |
| 109 |  René Mandri (EST) | Endura Racing | 17:30 |
| 110 | Grzegorz Stepniak (POL) | CCC - Polkowice | 17:39 |
| 111 | Adrián López Garrido (ESP) | | 18:43 |
| 112 | Daniel Dominguez Barragan (ESP) | Nsp - Ghost | 22:13 |
| 113 | Aritz Etxebarria Etxebarria (ESP) | Orbea | 22:24 |
| 114 | Piotr Gawronski (POL) | CCC - Polkowice | 22:40 |
| 115 | Evgeny Kovalev (RUS) | Rusvelo | 23:03 |
| 116 | Illart Zuazubiskar Gallastegi (ESP) | Orbea | 23:54 |
| 117 | Tom Leezer (NED) | Rabobank | 24:03 |
| 118 | Diogo Nunes (POR) | Carmin - Prio | 24:14 |
| 119 | Lucas Schädlich (GER) | Nsp - Ghost | 24:19 |
| 120 | Víctor Cabedo Carda (ESP) | Euskaltel - Euskadi | 24:44 |
| 121 | Fernando Reche Manzano (ESP) | | 25:01 |
| 122 | Antonio Cabello Baena (ESP) | Andalucia | 25:27 |
| 123 | Alexei Markov (RUS) | Rusvelo | 26:24 |
| 124 | Steffen Radochla (GER) | Nsp - Ghost | 27:36 |
