| 1 |  Alejandro Valverde Belmonte (ESP) | Movistar | 16:08:49 |
| 2 |  Rein Taaramäe (EST) | Cofidis | 00:03 |
| 3 |  Jérôme Coppel (FRA) | Saur - Sojasun | 00:08 |
| 4 |  Denis Menchov (RUS) | Team Katusha | 00:14 |
| 5 |  Sergey Lagutin (UZB) | Vacansoleil - DCM | 00:15 |
| 6 |  Tom Dumoulin (NED) | Argos - Shimano | 00:18 |
| 7 |  Fränk Schleck (LUX) | Radioshack - Nissan | 00:22 |
| 8 | Haimar Zubeldia Aguirre (ESP) | Radioshack - Nissan | 00:26 |
| 9 |  Maxime Monfort (BEL) | Radioshack - Nissan | 00:27 |
| 10 | Wilco Kelderman (NED) | Rabobank | 00:28 |
| 11 | Robert Gesink (NED) | Rabobank | zt |
| 12 | Bauke Mollema (NED) | Rabobank | 00:29 |
| 13 | Adrian Palomares Villaplana (ESP) | Andalucia | 00:31 |
| 14 |  Matthias Brändle (AUT) | Team Netapp | 00:32 |
| 15 | Igor Antón Hernandez (ESP) | Euskaltel - Euskadi | 00:35 |
| 16 | Mikel Astarloza Chaurreau (ESP) | Euskaltel - Euskadi | zt |
| 17 | Steven Kruijswijk (NED) | Rabobank | 00:36 |
| 18 | Jelle Vanendert (BEL) | Lotto - Belisol | 00:37 |
| 19 | David Le Lay (FRA) | Saur - Sojasun | 00:38 |
| 20 |  Simon Spilak (SLO) | Team Katusha | zt |
| 21 |  Matteo Carrara (ITA) | Vacansoleil - DCM | 00:39 |
| 22 | Eduard Vorganov (RUS) | Team Katusha | 00:43 |
| 23 | Daniel Moreno Fernández (ESP) | Team Katusha | 00:45 |
| 24 | Yannick Talabardon (FRA) | Saur - Sojasun | 01:04 |
| 25 |  Lucas Euser (USA) | Spidertech Powered By C10 | zt |
| 26 | Samuel Sanchez Gonzalez (ESP) | Euskaltel - Euskadi | 01:12 |
| 27 | Javier Moreno Bazan (ESP) | Movistar | 01:15 |
| 28 | Juan Manuel Gárate Cepa (ESP) | Rabobank | 01:19 |
| 29 | Brian Bulgac (NED) | Lotto - Belisol | 01:22 |
| 30 |  Simon Geschke (GER) | Argos - Shimano | 01:24 |
| 31 | Fabrice Jeandesboz (FRA) | Saur - Sojasun | zt |
| 32 |  Bartosz Huzarski (POL) | Team Netapp | 01:28 |
| 33 | Johannes Fröhlinger (GER) | Argos - Shimano | 01:29 |
| 34 | Marco Marcato (ITA) | Vacansoleil - DCM | 01:37 |
| 35 | Alexandre Geniez (FRA) | Argos - Shimano | 01:46 |
| 36 |  Andreas Dietziker (SUI) | Team Netapp | 01:50 |
| 37 | David De La Fuente Rasilla (ESP) | Caja Rural | 01:57 |
| 38 | Beñat Intxausti Elorriaga (ESP) | Movistar | 02:10 |
| 39 | Samuel Dumoulin (FRA) | Cofidis | 02:13 |
| 40 | Rob Ruijgh (NED) | Vacansoleil - DCM | 02:14 |
| 41 | Thomas Degand (BEL) | Accent.jobs – Willems Veranda’s | 02:30 |
| 42 |  Yukihiro Doi (JAP) | Argos - Shimano | 02:53 |
| 43 | Luis Angel Maté Mardones (ESP) | Cofidis | 03:09 |
| 44 | Linus Gerdemann (GER) | Radioshack - Nissan | 03:23 |
| 45 | Pim Ligthart (NED) | Vacansoleil - DCM | 04:14 |
| 46 | Antonio Piedra Perez (ESP) | Caja Rural | 04:16 |
| 47 | Yury Trofimov (RUS) | Team Katusha | 04:17 |
| 48 | Jens Voigt (GER) | Radioshack - Nissan | 04:19 |
| 49 | Egoi Martinez De Esteban (ESP) | Euskaltel - Euskadi | 04:52 |
| 50 | Aitor Galdos Alonso (ESP) | Caja Rural | zt |
| 51 | Markel Irizar Aranburu (ESP) | Radioshack - Nissan | zt |
| 52 |  Flavio Alejandro de Luna Dávila (MEX) | Spidertech Powered By C10 | 04:59 |
| 53 | Dennis Vanendert (BEL) | Lotto - Belisol | 05:06 |
| 54 | Caleb Fairly (USA) | Spidertech Powered By C10 | 05:09 |
| 55 | Francis De Greef (BEL) | Lotto - Belisol | 05:18 |
| 56 | Kevin Van Melsen (BEL) | Accent.jobs – Willems Veranda’s | zt |
| 57 | René Hooghiemster (NED) | Nsp - Ghost | 05:41 |
| 58 | Tristan Valentin (FRA) | Cofidis | 05:54 |
| 59 | Daniel Dominguez Barragan (ESP) | Nsp - Ghost | 06:00 |
| 60 | Oscar Freire Gomez (ESP) | Team Katusha | 06:05 |
| 61 | Gert Dockx (BEL) | Lotto - Belisol | 06:25 |
| 62 | Javier Ramirez Abeja (ESP) | Andalucia | 06:29 |
| 63 | Raymond Künzli (SUI) | Spidertech Powered By C10 | 06:55 |
| 64 |  Michael Matthews (AUS) | Rabobank | 06:56 |
| 65 | Jean-Marc Marino (FRA) | Saur - Sojasun | 07:09 |
| 66 |  Fabricio Ferrari Barcelo (URU) | Caja Rural | 07:14 |
| 67 | Sergej Fuchs (GER) | Nsp - Ghost | 07:22 |
| 68 | Gregory Habeaux (BEL) | Accent.jobs – Willems Veranda’s | 07:27 |
| 69 | Daniele Bennati (ITA) | Radioshack - Nissan | 07:43 |
| 70 | Juan Jose Oroz Ugalde (ESP) | Euskaltel - Euskadi | 07:53 |
| 71 | Jesus Rosendo Prado (ESP) | Andalucia | 07:55 |
| 72 | Reto Hollenstein (SUI) | Team Netapp | 07:56 |
| 73 | Mickaël Buffaz (FRA) | Cofidis | 08:13 |
| 74 | Jose Ivan Gutierrez Palacios (ESP) | Movistar | 08:19 |
| 75 | Juan José Lobato del Valle (ESP) | Andalucia | 08:41 |
| 76 |  Oleg Chuzhda (UKR) | Accent.jobs – Willems Veranda’s | zt |
| 77 | Gustavo César Veloso (ESP) | Andalucia | 08:53 |
| 78 | Gorka Izagirre Insausti (ESP) | Euskaltel - Euskadi | 08:57 |
| 79 | Markus Fothen (GER) | Nsp - Ghost | 09:28 |
| 80 | Yann Huguet (FRA) | Argos - Shimano | 09:43 |
| 81 | Gaëtan Bille (BEL) | Lotto - Belisol | 09:45 |
| 82 | Nicolas Vogondy (FRA) | Cofidis | 09:53 |
| 83 | Francisco Javier Aramendia Llorente (ESP) | Caja Rural | 10:03 |
| 84 | Grischa Niermann (GER) | Rabobank | 10:34 |
| 85 | Steven Caethoven (BEL) | Accent.jobs – Willems Veranda’s | 10:47 |
| 86 | Jorge Azanza Soto (ESP) | Euskaltel - Euskadi | 10:51 |
| 87 | Daniel Schorn (AUT) | Team Netapp | 10:52 |
| 88 | Luca Paolini (ITA) | Team Katusha | 11:04 |
| 89 | Antonio Cabello Baena (ESP) | Andalucia | 11:10 |
| 90 |  Leonardo Fabio Duque (COL) | Cofidis | 12:15 |
| 91 | Jimmy Engoulvent (FRA) | Saur - Sojasun | 12:20 |
| 92 |  Ryan Roth (CAN) | Spidertech Powered By C10 | 12:35 |
| 93 | Kenny Van Hummel (NED) | Vacansoleil - DCM | 12:50 |
| 94 |  Jan Bárta (CZE) | Team Netapp | 13:50 |
| 95 | Stéphane Poulhies (FRA) | Saur - Sojasun | 14:14 |
| 96 | Stefan Van Dijk (NED) | Accent.jobs – Willems Veranda’s | 14:16 |
| 97 | Imanol Erviti Ollo (ESP) | Movistar | 14:49 |
| 98 |  Manuel Antonio Cardoso Leal (POR) | Caja Rural | 15:09 |
| 99 | Ryan Anderson (CAN) | Spidertech Powered By C10 | 15:17 |
| 100 | Igor Romero Etxebarria (ESP) | Caja Rural | 15:30 |
| 101 | Jurgen Van Goolen (BEL) | Accent.jobs – Willems Veranda’s | 15:51 |
| 102 |  Vasil Kiryienka (BLR) | Movistar | 16:20 |
| 103 | Léo Menville (FRA) | Nsp - Ghost | 16:24 |
| 104 | Jacob Fiedler (GER) | Nsp - Ghost | 17:48 |
| 105 | Will Routley (CAN) | Spidertech Powered By C10 | 17:56 |
| 106 | Patrick Gretsch (GER) | Argos - Shimano | 18:22 |
| 107 |  Ignatas Konovalovas (LTU) | Movistar | 22:14 |
| 108 | Steffen Radochla (GER) | Nsp - Ghost | 25:50 |
